Thermal decomposition of ammonium perchlorate catalyzed with CuO nanoparticles

Ammonium perchlorate (APC) is the most common oxidizer in use for solid rocket propulsion systems. However its initial thermal decomposition is an endothermic process that requires 102.5 J·g⁻¹. This manner involves high activation energy and could render high burning rate regime. This study reports on the sustainable fabrication of CuO nanoparticles as a novel catalyzing agent for APC oxidizer. Colloidal CuO nanoparticles with consistent product quality were fabricated by using hydrothermal processing. TEM micrographs demonstrated mono-dispersed particles of 15 nm particle size. XRD diffractogram demonstrated highly crystalline material. The synthesized colloidal CuO particles were effectively coated with APC particles via co-precipitation by using fast-crash solvent–antisolvent technique. The impact of copper oxide particles on APC thermal behavior has been investigated using DSC and TGA techniques. APC demonstrated an initial endothermic decomposition stage at 242 °C with subsequent two exothermic decomposition stages at 297.8 °C and 452.8 °C respectively. At 1 wt%, copper oxide offered decrease in initial endothermic decomposition stage by 30%. The main outcome of this study is that the two main exothermic decomposition peaks were merged into one single peak with an increase in total heat release by 53%. These novel features can inherit copper oxide particles unique catalyzing ability for advanced highly energetic systems.     

预警探测体系作战效能评估框架

首先阐述了预警探测体系及其效能评估的概念,根据预警探测体系及其作战任务的特点,建立了效能评价指标体系,并给出了部分效能指标的评估计算模型,最后提出了预警探测体系作战效能评估的框架和一般过程.     

REFLECTIONS ON THE INTEGRATION OF THE MILITARY IN SOUTH AFRICA

This paper explores the contribution of the African Union (AU) to human security promotion in Africa. It contends that human security concerns informed the formation of the AU. Through the efforts of the AU Commission, the African ruling elite and policy-makers have become aware of human security doctrines. Human security ideas have been integrated into AU binding agreements, declarations, decisions and policies. The commission is now in the difficult, yet most important, phase of trying to persuade significant numbers of the African ruling elite and civil society to accept human security as a guiding principle and the desirable norm. Through the African Citizens' Directorate (CIDO), the commission is using indigenous African civil society groups to institutionalise human security doctrines in Africa. The commission faces serious challenges in its efforts to make human security the only security norm. While member states of the AU that have never been comfortable with the introduction of human security doctrines into the continental integration project are tacitly undermining the CIDO's ability to work with civil society groups to institutionalise the doctrines in Africa, the leaders who enthusiastically supported the integration of human security doctrines into the documents and work of the AU have seemed in recent times to be less resolute in their support of AU Commission's human security work.     

多机器人编队控制研究

多机器人编队控制是多机器人协调控制中一个最具有挑战性的研究问题.首先简要概述了多机器人编队问题的研究现状.从面向问题的角度出发,将编队问题分解成编队角色分配、队形生成、队形变换与选择、编队跟踪4个子问题,并针对每个子问题,总结了现有的研究方法.最后,特别强调编队控制中的网络问题并指明未来的研究万向.     

导频设计的MIMO-OFDM改进信道估计算法

为提高系统的传输效率并改善信道估计的性能,提出了一种结合优化导频设计的分段带阻滤波算法.采用优化的导频设计,该算法在少量增加计算复杂度的基础上,能够进一步提高信道估计的性能,与实际中广泛应用的经典时域滤波算法相比,具有更高的估计精度.仿真结果证明该算法适用于不同的信道环境,尤其在低信噪比的条件下,该算法能够明显降低信道估计的MSE.     

Optimal pricing and scheduling control of product shipping

In this article, we seek to understand how a capacity‐constrained seller optimally prices and schedules product shipping to customers who are heterogeneous on willingness to pay (WTP) and willingness to wait (WTW). The capacity‐constrained seller does not observe each customer's WTP and WTW and knows only the aggregate distributions of WTP and WTW. The seller's problem is modeled as an M/M/N_s queueing model with multiclass customers and multidimensional information screening. We contribute to the literature by providing an optimal and efficient algorithm. Furthermore, we numerically find that customers with a larger waiting cost enjoys a higher scheduling priority, but customers with higher valuation do not necessarily get a higher scheduling priority. © 2015 Wiley Periodicals, Inc. Naval Research Logistics 62: 215–227, 2015     

积极贯彻军民融合式发展战略 推进海军装备体系建设科学发展

推进海军装备体系建设领域内军民融合式发展是新形势下加快海军战斗力生成模式转变的重大举措,事关海军长远发展。文章从推进海军武器装备军民融合式发展的重要性入手,分析了当前海军武器装备体系建设领域军民融合工作面临的形势,提出了研建信息交流平台、优化计划编制、更新采办策略、改进合同管理、完善监管手段等对策建议。     

基于复杂适应系统理论的一体化联合作战研究

复杂适应系统理论为我们研究军事系统提供了崭新的视角,避免了传统的基于还原论方法研究军事系统机械分隔忽略系统要素之间相互作用的问题,可以得到军事系统全面准确的认识,对于深入研究一体化联合作战的本质内涵、基本特征和主要方法,尽快形成一体化联合作战的理论体系具有重要意义。文章通过分析军事系统特点得出军事系统是复杂适应系统的结论,在此基础上,从复杂适应系统理论的角度分析了一体化联合作战的内涵及提高军事系统一体化联合作战能力需要重点解决的四个问题。     

On a class of multiple failure mode systems

The primary objective of this work is to introduce and perform a detailed study of a class of multistate reliability structures in which no ordering in the levels of components' performances is necessary. In particular, the present paper develops the basic theory (exact reliability formulae, reliability bounds, asymptotic results) that will make it feasible to investigate systems whose components are allowed to experience m ≥ 2 kinds of failure (failure modes), and their breakdown is described by different families of cut sets in each mode. For illustration purposes, two classical (binary) systems are extended to analogous multiple failure mode structures, and their reliability performance (bounds and asymptotic behavior) is investigated by numerical experimentation. © 2002 Wiley Periodicals, Inc. Naval Research Logistics 49: 167–185, 2002; DOI 10.1002/nav.10007     

A strategic model for state compliance verification

The theory of directed graphs and noncooperative games is applied to the problem of verification of State compliance to international treaties on arms control, disarmament and nonproliferation of weapons of mass destruction. Hypothetical treaty violations are formulated in terms of illegal acquisition paths for the accumulation of clandestine weapons, weapons‐grade materials or some other military capability. The paths constitute the illegal strategies of a sovereign State in a two‐person inspection game played against a multi‐ or international Inspectorate charged with compliance verification. The effectiveness of existing or postulated verification measures is quantified in terms of the Inspectorate's expected utility at Nash equilibrium. A prototype software implementation of the methodology and a case study are presented. © 2016 Wiley Periodicals, Inc. Naval Research Logistics 63: 260–271, 2016